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The atmospheres of novae at early times in their outbursts are very extended, expanding shells with low densities. Models of these atmospheres show that NLTE effects are very important and must be included in realistic calculations. We have, therefore, been improving our atmospheric studies by increasing the number of ions treated in NLTE. One of the most important ions is Fe II which has a complex structure and numerous lines in the observable spectrum. In this paper we investigate NLTE effects for Fe II for a wide variety of parameters. We use a detailed Fe II model atom with 617 level and 13675 primary lines, treated using a rate-operator formalism. We show that the radiative transfer equation in nova atmospheres {\em must} be treated with sophisticated numerical methods and that simple approximations, such as the Sobolev method, {\em cannot} be used because of the large number of overlapping lines in the co-moving frame. Our results show that the formation of the Fe II lines is strongly affected by NLTE effects. For low effective temperatures, \Teff < 20,000\,K, the optical Fe II lines are most influenced by NLTE effects, while for higher \Teff the UV lines of Fe II are very strongly affected by NLTE. The departure coefficients are such that Fe II tends to be overionized in NLTE when compared to LTE. Therefore, Fe II-NLTE must be included with sophisticated radiative transfer in nova atmosphere models in order to reliably analyze observed nova spectra

The Effects of Fe II Non-LTE on Nova Atmospheres and Spectra