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The curing rate over one kind of MnO 2  was relative slow for traditional polysulfide sealing, and it was difficult to flexibly adjust induction time and curing rate with low cost. The physical mixture of two kinds of MnO 2  showed much rapid curing rate than that of corresponding single MnO 2  alone, particularly, the physical mixture of δ-MnO 2  and α-MnO 2  showed superior curing performance to δ-MnO 2  and α-MnO 2  and lower curing rate than that of δ-MnO 2  by photo assistance. The efficient and controllable polysulfide sealing can be achieved by facile physical mixture of different crystalline forms of MnO 2  and/or turning on/off light.

Facile, efficient and controllable polysulfide sealing over physical mixture of different crystalline forms of MnO 2