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Reaction between benzoimidazole-2-thiol and aroyl chlorides with potassium selenocyanate in the presence of catalytic amounts of  N -methylimidazole under solvent-free conditions provided a simple and efficient one-pot route for the synthesis of 4-aryl-1-thia-3,4a,9-triazafluorene-2-selones. The solvent free reaction is characterized by mild conditions, short reaction times, easy work-up, and high product yields.

An efficient and one-pot synthesis of 4-aryl-1-thia-3,4a,9-triazafluorene-2-selones