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Pentamethylcyclopentadienyldicarbonyl iron thiocarboxylato complexes Cp*Fe(CO) 2 SCOR {Cp* = C 5 Me 5 , R = Me ( 2a ), Ph ( 2b ) ,  C 4 H 3 O ( 2c ), C 4 H 3 S ( 2d ) ,  CH 2 CH 2 COCl ( 2e )} are synthesized from the reaction of Cp*Fe(CO) 2 SH ( 1 ) with the corresponding chloride acids. Complex  1  is obtained from the treatment of [Cp*Fe(CO) 2 ] 2  with elemental sulfur (S 8 ) followed by hydrolysis on silica. The hydrolysis of  2e  with trace amount of water gave the corresponding acid derivative Cp*Fe(CO) 2 SCOCH 2 CH 2 COOH ( 3 ). All new complexes have been characterized by IR,  1 H NMR spectroscopy and elemental analysis. The solid state structures of  1  and  3  are confirmed by X-ray analysis.

Pentamethylcyclopentadienyl iron thiocarboxylato complexes: synthetic and characterization study