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Homoleptic pyridyl-3(N) functionalized dithiocarbamate complexes namely, [Zn(L1) 2 ] 21  (L1 = (C 5 H 4 NCH 2 ) 2 NCS 2 ) and [Cd(L2) 2 ]  ∞2  (L2 = CH 3 C 6 H 4 CH 2 NCS 2 CH 2 C 4 H 3 O) have been synthesized and characterized by elemental analysis and different spectroscopic techniques. Single crystal structural studies reveal that compound  1  is binuclear while,  2  is polymeric structure. The presence of weak interactions between complexes and solvent molecules in the lattice results in one-dimensional and three-dimensional supramolecular structures of  1  and  2  respectively. In the case of complex  2 , a rare and significant S···Cl chalcogen bonding interaction was found, which involve the solvent molecule in chain motifs. Complex  2  is a unique example of homoleptic metal dithiocarbamate complexes exhibiting such types of interactions. Complexes showed emission in the solid state. The TGA studies of complexes revealed that complex  1  would be a good precursor for the preparation of ZnS thin film  via  metal organic chemical vapor deposition (MOCVD).

journal of sulfur chemistry

Co-operative influence of co-crystallized solvent in sustaining supramolecular architectures of Zn(II)/Cd(II) homoleptic pyridyl functionalized dithiocarbamates complexes  via  non-covalent interactions