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An extremely efficient synthetic method for the preparation of 2-aminobenzothiazole derivatives starting from arylthioureas by using  N -iodosuccinimide has been reported. This protocol features a mild reaction conditions, a short reaction time, and metal-free oxidative conditions for C ( sp2 )-S bond construction.

N -Iodosuccinimide mediated intramolecular oxidative C( sp 2 )-S bond formation for the synthesis of 2-aminobenzothiazole derivatives