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Solid polymer electrolytes were prepared using polymethyl methacrylate (PMMA), ethylene carbonate (EC), lithium trifluoroethane-sulfonate (LiTf), magnesium trifluoro-methanesulfonate (MgTf 2 ). The ionic conductivity was measured at 30 °C as 6.17 × 10 −6  and 1.83 × 10 −4  S cm −1 , respectively. The ionic mobility ( μ ), charge carrier diffusion coefficient ( D ) and the ion number density ( n ) of the samples have been calculated to understand the effect of these parameters on the ionic conductivity. The experimentally obtained values ofandare compared with theoretical calculations. The PMMA-EC-MgTf 2  sample exhibits higher dielectric constant compared to PMMA-EC-LiTf. The MgTf 2  containing sample also exhibits a higher transference number.

Determination of transport properties for polymer electrolytes containing LiTf and MgTf 2 salts