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A hydrothermal blending method was employed to successfully fabricate the SBA-16/α-MoO 3  catalyst. In comparison with α-MoO 3  and α-MoO 3 /SBA-16, SBA-16/α-MoO 3  showed good catalytic activity in the conversion of synthetic diphenyl carbonate. At ambient pressure and a reaction temperature of 180 °C, the dimethyl carbonate (DMC) conversion reached 78.5% and the selectivity for diphenyl carbonate (DPC) was over 46.5%. The study was revealed that the SBA-16/α-MoO 3  catalyst effectively regulated the Si distribution on surface of SBA-16, which was crucial to decrease the carbon deposition formation and increase the reaction rate.

Enhanced catalytic behavior for synthesis of diphenyl carbonate over SBA-16 composited with α-MoO 3