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Two novel Co(II) and Ni(II) complexes Co(dpza) 2  ( 1 ) and Ni(dpza) 2  ( 2 ) (Hdpza is 2,2-di(1 H -pyrazol-1- yl )acetic acid) were successfully synthesized  via  solvothermal method. The two complexes namely,  1  and  2  are isostructural exhibiting lantern-shaped configurations as illustrated by the structural analysis. The structures of the two complexes have been determined by single-crystal X-ray diffraction, FT-IR, and TGA. Magnetic property of  1  in the 2–300 K also has been investigated which displays dominant ferromagnetic behavior. Hirshfeld surface analysis reveals that the main interactions for complex  two  are O···H/H···O and H···H contacts.

molecular crystals and liquid crystals

Lantern-shaped cobalt(II) and nickel(II) complexes based on a tripodal bis(pyrazol-1- yl )acetate ligand: crystal structure, magnetic property and Hirshfeld surface analysis