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The paper presents the structural-energy, electrically conductive and polarization properties of biintercalant clathrate GaSe≪NaNO 2 &gt; +&lt;FeCl 3 ≫. The existence of two modifications of the crystal structure with interplanar distances c 1  = 16.072 Å and c 2  = 15.977 Å was established by X-ray diffractometry. The сurrent-voltage characteristics of the biitercalant clathrate GaSe≪NaNO 2 &gt; +&lt;FeCl 3 ≫ acquires a hysteresis form, which indicates the accumulation of electric charge at the interfacial boundaries. The spectrum of impurity energy levels was established by the method of thermally stimulated discharge with short-circuited contacts in the temperature range from 240 to 340 K, which testifies to the relaxation of the hetero-charge and the quasi-continuity of energy states.

Biintercalate formed on the basis of 2D semiconductor matrix, ferroelectric and ferromagnetic phases