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An efficient heterostructure, compactly durian-like mischcrystal TiO 2 /graphene containing the anatase and rutile phase, was prepared  via  a seed-induced synthesis. The TiO 2  seed crystal on the surface of graphene plays a vital role in the formation of durian-like mischcrystal TiO 2 /graphene. The scattered rutile-TiO 2  nanoparticles interspersed on the crystal planes of anatase-TiO 2  tetrahedron. This novel configuration improved the BET specific surface area to 71.28 m 2 /g and the visible light response range of multiphase TiO 2 /graphene. The heterostructure and the synergistic effect between the anatase and rutile TiO 2  could transfer the electron, leading to suppress the electron-hole recombination. After 3 h irradiation, the desulfurization rate of durian-like mischcrystal TiO 2 /graphene photocatalyst reached 83.5% for dibenzothiophene.

Seed-induced synthesis of durian-like mischcrystal TiO 2 /graphene as an efficient photocatalyst for desulfurization