English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

We report the formation of an interconnected, three-dimensional, mesoporous polymeric fullerene oxide framework via thermal [3 + 2] cyclo-additions of monomeric C 60  and fullerene oxides (C 60 O n ), formed upon thermal decomposition of C 60 Br 24,  causing the eliminations of bromine atoms in an oxygen atmosphere at an elevated temperature of 200 °C. The newly formed mesoporous fullerene oxide framework is found to be a low bandgap semiconductor capable of acting as a photocatalyst similar to graphitic C 3 N 4 . The sunlight-assisted photocatalytic degradation of the methylene blue dye is demonstrated. To have a better understanding of the mechanism of the [3 + 2] cyclo-additions of monomeric C 60  and fullerene oxides, a theoretical investigation has been carried out and the energetics of the reaction C 60 O + C 60  → C 120 O is calculated.

Preparation of mesoporous poly(fullerene oxide) framework by thermal [3 + 2] cycloadditions and its application as a semiconductor photocatalyst