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This review analyses the account of biological (microalgae) and synthetic (bio-polymeric adsorbents) elements to compass the treatment efficiencies of various water pollutants and mechanisms behind them. While considering pollutant removal, both techniques have their own merits and demerits. Microalgal-based methods have been dominantly used as a biological method for pollutant removal. The main limitations of microalgal methods are capacity, scale, dependence on variables of environment and duration of the process. Biopolymers on the other hand are naturally produced, abundant in nature, environmentally safe and biocompatible with cells and many times biodegradable. Algal immobilization in biopolymers has promoted the reuse of cells for further treatment and protected cells from toxic environment monitoring and controlling the external factors like pH, temperature and salinity can promote the removal process while working with the mentioned technologies. In this review, a mechanistic view of both these techniques along with integrated approaches emphasizing on their loopholes and possibilities of improvement in these techniques is represented. In addition to these, the review also discusses the post-treatment effect on algal cells which are specifically dependent on pollutant type and their concentration. All these insights will aid in developing integrated solutions to improve removal efficiencies in an environmentally safe and cost-effective manner. Novelty statement  The main objective of this review is to thoroughly understand the role of micro-algal cells and synthetic adsorbents individually as well as their integrative effect in the removal of pollutants from wastewater. Many reviews have been published containing information related to either removal mechanism by algae or synthetic adsorbents. While in this review we have discussed the agents, algae and synthetic adsorbents along with their limitations and explained how these limitations can be overcome with the integration of both the moieties together in process of immobilization. We have covered both the analytical and mechanistic parts of these technologies. Along with this, the post-treatment effects on algae have been discussed which can give us a critical understanding of algal response to pollutants and by-products obtained after treatment. This review contains three different sections, their importance and also explained how these technologies can be improved in the future aspects.

Microalgae and bio-polymeric adsorbents: an integrative approach giving new directions to wastewater treatment