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Two new tigliane- and daphnane-type diterpenoids, given the trivial names daphnegens A–B  (1 – 2)  were isolated from the buds of  Daphne genkwa . Their structures were assigned on the basis of extensive spectroscopic. The absolute configurations of both compounds were determined by comparison of their calculated and experimental CD curves. In addition, compounds  1 – 2  were tested for their cytotoxic activities against MCF-7 and HepG-2 human cancer cell lines, and compound  2  showed remarkable cytotoxic activity against HepG-2 cell line with the IC 50  value of 11.5  μ M.

Tigliane-and daphnane-type diterpenoids from the buds of Daphne genkwa with their cytotoxic activities