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Salvia mellifera,  native to California, Baja California, and Mexico, is a medicinal herb traditionally used to relieve pain, body aches, including chronic pain. A detailed phytochemical investigation of aerial parts of  S. mellifera  was accomplished to find species-specific markers and to differentiate the closely related, often (un)intentionally substituted with  S. apiana . A total of 22 metabolites, including flavonoids ( 1 – 14 ), triterpenoids ( 15 – 18 ), diterpenoids ( 19 – 21 ), and phenylpropanoid ( 22 ), were isolated and characterized thoroughly. Among the isolates, eupatorin 3′- O -glucopyranoside ( 1 ) was identified as undescribed phytochemical and detailed structure elucidation was achieved through extensive NMR and mass spectral data analysis.

Eupatorin 3′- O -glucopyranoside, a trimethoxyflavonoid glucoside from the aerial parts of Salvia mellifera