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The present study has tentatively elucidated the structure of two acylated polyoxypregnane glycosides from  Caralluma quadrangula  (Forssk.) N.E.Br. ( CQ ). The analyses were performed using an electrospray-ionization quadrupole time-of-flight (ESI-Q-TOF) mass spectrometer in positive ionization modes to explore fragmentation pathways. The used ionization mode provided consistent and/or complementary information for most of the pregnane glycosides, their fragmentation sequences, and their aglycones. Presumably, this is due to higher efficiency, sensitivity, and better selectivity of the mass spectrometry-based method. The present experimental and theoretical report deals with the characteristic fragmentation behaviors of two acylated polyoxypregnane glycosides CQ1 and CQ2 from the aerial parts of C. quadrangular. A DFT Study was performed to elucidate the position of ikemoyl, and benzoyl residues in compounds CQ1 and CQ2, respectively.

natural product research

Fingerprinting of two an acylated polyoxypregnane glycosides from  Caralluma quadrangula  (Forssk.) N.E.Br. using UPLC-ESI-Q-TOF and computational study