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Chemical investigation of endophytic fungus  Aspergillus fumigatus  HQD24, isolated from the flower of  Rhizophora mucronata  led to the isolation of eight alkaloids, including pyripyropene A ( 1 ), 1,11-dideacetyl-pyripyropene A ( 2 ), pyripyropene E ( 3 ), chaetominine ( 4 ), tryptoquivaline J ( 5 ), fumitremorgin C ( 6 ), 1-acetyl-β-carboline ( 7 ), and nicotinic acid ( 8 ). Their structures were unambiguously elucidated on the basis of extensive spectroscopic data and comparison with the data of literature. Compound  2  was known as a synthetic product and isolated as a natural product for the first time. The immunosuppressive and cytotoxic activities of all isolated compounds were evaluated.

Alkaloids from endophytic fungus Aspergillus fumigatus HQD24 isolated from the Chinese mangrove plant Rhizophora mucronata