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Two new sesquiterpenes, named selina-4(14),7,11-trien-9-ol ( 1 ) and selina-4(14),11-dien-7-ol ( 2 ), along with two known compounds were isolated from rhizomes of  Atractylodes macrocephala  Koidz. All structures were assigned on the basis of detailed spectroscopic analyses. The absolute configuration of  1  was established by TDDFT-ECD calculations. Compound  1  was found to moderately inhibit LSD1 activity with IC 50  value of 34.0 μM. Compounds  1  and  4  exhibited a regulate effect on Keap1-Nrf2-ARE pathway.

Two new sesquiterpenes from the rhizomes of Atractylodes macrocephala and their biological activities