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Three new andrastin derivatives, 10-formyl andrastone A ( 1 ), 10-demethylated andrastone A ( 2 ) and andrastin G ( 3 ), together with four known andrastin analogues ( 4 - 7 ) were isolated from an endophytic fungus  Penicillium vulpinum . Their structures were determined by 1 D, 2 D NMR, and the absolute configurations were further determined by experimental and calculated ECD spectra. Compound  5  exhibited significant antibacterial activity against  Bacillus paratyphosus  B with an MIC value of 6.25  µ g·mL −1 . Compounds  2  and  6  showed remarkable inhibitory activities against  Bacillus megaterium  with the MIC value of 6.25  µ g·mL −1 , respectively.

Three new andrastin derivatives from the endophytic fungus Penicillium vulpinum