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A new porous 3D coordination polymer (CP), namely [Mn 2 (Htpim) 2 (odpa)]·8H 2 O (1, Htpim = 2,4,5-tri(4-pyridyl)-imidazole, odpa = 4,4′-oxydiphthalate), was successfully synthesized. Furthermore, complex 1 could be applied as a probe displaying good ion sensing property of Cr 3+  ion by fluorescence quenching. For the treatment of the temporary osteoporosis of the hip (TOH), the biological function of the compound was evaluated. Annexin V-FITC/PI assay was performed to measure the bone marrow stem cells’ apoptosis after compound treatment. Besides, western blot was utilized to determine the signaling pathway of the wnt/β-catenin activation in bone marrow stem cells.

materials technology

A new Mn(II)-based coordination polymer: selective ion-sensing property and treatment activity on temporary osteoporosis of the hip by activating wnt/β-catenin signaling pathway in bone marrow stem cells