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Low-fired MgTi 0.9 Zr 0.1 O 3 - x wt%2LiF-B 2 O 3 -2Bi 2 O 3  (LBB, 1.0 ≤  x  ≤ 9.0) ceramics are fabricated via a conventional solid-state reaction route. The effects of LBB additive on phase composition, sintering behavior and dielectric performance of MgTi 0.9 Zr 0.1 O 3 -based ceramics are researched. Sintered samples displayed a MgTiO 3  phase accompanying with Mg 2 TiO 4  and Bi 2 O 3  as the second phase. LBB doping successfully reduced sintering temperature of MgTi 0.9 Zr 0.1 O 3 -based ceramic from 1300 °C to 850 °C. The dielectric property of MgTi 0.9 Zr 0.1 O 3 -LBB systems depended on LBB additive. Typical, MgTi 0.90 Zr 0.10 O 3 -5.5 wt%LBB ceramic exhibited good dielectric property of  ε r= 18.4,  Q  ×  f  = 23100 GHz and  τ f= −52.8 ppm / °C at 900 °C.

Dielectric Properties of Low-Fired MgTi 0.9 Zr 0.1 O 3 Ceramics with LBB Additive for LTCC Applications