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The enzyme-promoted hydrolysis of racemic ester derivatives of PTA  11  and its  P -sulfide  12  gave unreacted esters and corresponding acids, which were converted into ester, in moderate yield depending on the solvent and enzyme applied. However, in all cases the products were racemic mixtures.

Attempts at the enzymatic synthesis of chiral ester derivatives of 1,3,5-triaza-7-phosphaadamantane (PTA)