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Recent achievements in asymmetric synthesis of α-polyfluoroalkylated aminophosphonic acid derivatives from C-phosphorylated imines are summarized. The synthetic potential of fluoroalkylated iminophosphonates was revealed by their easy diastereoselective functionalization (hydrogenation, proline-catalyzed Mannich reaction with acetone, cycloaddition with diazomethane) to afford optically active compounds bearing biorelevant α-polyfluoroalkylated α-aminophosphonic fragment.

C-phosphorylated imines in synthesis of non-racemic α-fluoroalkylated aminophosphonic acid derivatives