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We report a novel diiron propane-1,3-dithiolate complex [Fe 2 (CO) 5 PH(C 10 H 15 ) 2 ( μ -SCH 2 CH 2 CH 2 S)] containing a di-1-adamantylphosphine ligand. Trimethylamine N-oxide-induced decarbonylation of complex [Fe 2 (CO) 6 ( μ -SCH 2 CH 2 CH 2 S)] followed by reaction with di-1-adamantylphosphine yielded the target product in 86% yield. The title compound was identified by spectroscopy, elemental analysis, as well as further determined by single crystal X-ray diffraction analysis. Electrochemical properties were studied by cyclic voltammetry without or with HOAc. Interestingly, the fungicidal activity of the title compound showed moderate activity against  Phytophthora infestans ,  Pyricularia oryae ,  Botrytis cinerea , and  Physalospora piricola .

phosphorus, sulfur, and silicon and the related elements

Di-1-adamantylphosphine-containing diiron propane-1,3-dithiolate pentacarbonyl complex: Synthesis, structure, electrochemistry, and fungicidal activity