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The thermoluminescence properties of aluminium oxide (alumina) implanted with 80 keV argon ions at fluences in the range ofwere investigated. The unimplanted and implanted samples were irradiated at a dose of 40 Gy and heated at a rate of 1°C/s. The glow curve of unimplanted and implanted samples shows 5 distinct peaks; the main dosimetric peak and four other peaks of lower intensity. In this study, our analysis has focussed on the main dosimetric peak located at 180°C, 191°C, 177°C, 208°C, 219°C and 207°C for the unimplanted sample and implanted samples respectively. It was observed that the TL intensity decreases with fluence of implantation. This suggests that ion implantation decreases the concentration of electron traps responsible for thermoluminescence. It can also be suggested that competition effects involving radiative pathways and non-radiative competitor traps may lead to a low thermoluminescence signal in the implanted samples in comparison to the unimplanted thermoluminescence signal. These competitive processes will tend to favour first-order kinetics, and consequently lead to a strong stability of the glow curve shapes. The creation of defect clusters as well as extended defects could also be responsible for the reduction in TL signal. The stopping and range of atoms in matter (SRIM) was used to evaluate the ion impact parameters including ion range, vacancy distribution and energy loss in Al 2 O 3 . Subsequent to ion implantation, it was found that the number of oxygen vacancies which are related to electron traps are higher than the number of aluminium vacancies. Kinetic analysis was carried out by means of the initial rise, Chen’s peak shape, various heating rate, the whole glow curve, glow curve fitting and isothermal decay methods. The activation energy was found to be aroundand the frequency factor to be of the orderregardless of the implantation fluence. The dosimetric features of samples were also investigated at doses in the range of 40–200 Gy. Samples generally showed a superlinear response at doses less than 140 Gy and sublinear response at doses higher than 160 Gy.

radiation effects and defects in solids

Evaluation of argon ion impact parameters in aluminium oxide by means of SRIM program and investigation of the effect of argon ion implantation on the thermoluminescence properties aluminium oxide