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One of the synthetic intermediates is used in many organic transformations. We have developed highly efficient  N -formylation of anilines ( 3a – l ) under solvent- and catalyst free using 150 W tungsten lamp under visible light. High yields of products, simple work-up and environmental benign conditions are the attractive features of the present methodology. All synthesized ( 3a – l ) compounds were characterized by IR,  1 H NMR and mass spectral analysis.

Visible Light Induced Synthesis of N -Formylation of Anilines Under Solvent and Catalyst Free Condition