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1,3-Dipolar cycloaddition reaction of 3-hydroxy-1-(2-oxo-2-phenylethyl) pyridinium bromide ( 1 ) or 3-hydroxy-1-(3-nitrobenzyl) pyridinium chloride ( 2 ) with trimethylvinylsilane, methylsulfonyl chloride, and vinyl triphenylphosphonium bromide under the influence of sonoenergy leads to form six cycloadducts ( 3 )–( 8 ). The novel cycloadducts were characterized using Fourier transform infrared (FTIR) spectroscopy, mass spectroscopy (MS), and nuclear magnetic resonance ( 1 H-NMR).  In situ  formation of polyaniline (PANI) composites in the presence of 0.1 g of each cycloadduct (CYC) led to form eight PANI/CYC composites ( 9 )–( 16 ). The newly synthesized composites were characterized by using transmission electron microscopy. All composites showed high electrical conductivity compared with PANI itself. The potential of new composites as anti-biofouling agents was evaluated. Compounds were observed to be the most potent antimicrobial/antifouling agents considering their toxicity against non-target sea organisms.

polycyclic aromatic compounds

Polyaniline/Aza-Bicyclo Composites Containing P, S, and Si Atoms: Synthesis, Characterization, Molecular Orbital Calculations, Electrical Conductivity, and Biocidal Activities against Some Biofouling-Causing Organisms