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A series of xanthenediones,  3  were synthesized from benzyl alcohols,  1  via TEMPO/CuCl 2  catalyzed aerobic oxidation, and sequential cyclization with cyclohexane-1,3-dicarbonyl compounds has been achieved. Similarly, the acridine-diones,  5  were obtained using a similar strategy from various benzyl alcohols. The strategy offers a simple experimental procedure, ease of access, within short reaction period, without the use of any hazardous solvents, and expensive chemicals.

polycyclic aromatic compounds

Facile Synthesis of Xanthenesdiones and Acridinediones through TEMPO/CuCl 2  Catalyzed Aerobic Oxidation of Benzyl Alcohols and Cyclization with Cyclohexane-1,3-Dicarbonyl Compounds