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Kanjone ( 1 ), a bioactive furanoflavone and a potent biomolecule, was first isolated from  Pongamia pinnata  (L.). Herein, we have developed two approaches to synthesize kanjone as well as its natural analogues 6-methoxyisopongaglabol ( 2 ) and 6,3'-dimethoxy-[2″,3″:7,8]furanoflavone ( 3 ) starting from khellin and 3-hydroxy-4-methoxy-benzaldehyde, respectively.

First total syntheses of kanjone and its natural analogues