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Marine natural products are promising sources of green antifoulants. Here, a new compound ( 1 ) was isolated from the soft coral  Sinularia flexibilis . This compound, another nine cembranoids ( 2 – 10 ) from  S. flexibilis , and three eunicellin-type diterpenoids ( 11 – 13 ) from the gorgonian  Muricella  sp. were tested for antifouling activity against larval settlement of the bryozoan  Bugula neritina . Compounds  2 ,  3 ,  4 ,  9 ,  12 , and  13  exhibited significant antifouling activity, with EC 50  values of 18.2, 99.7, 67.9, 35.6, 33.9, and 49.3 μM, respectively. Analysis of the structure-activity relationships suggested that the hydroxy group at C-13 in compound  4  reduced its antifouling activity.

Antifouling activity of terpenoids from the corals Sinularia flexibilis and Muricella sp. against the bryozoan Bugula neritina