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Peridecalins C and D ( 1  and  2 ), one decalin and one oxygen-decalin containing polyketide-amino acid hybrids with 5/6/6 ring system, was isolated from a genetic mutant of  Periconia  sp. F-31. Their structures were elucidated through extensive spectroscopic data analysis, including 1 D/2D NMR and HR-MS spectra. Biosynthetically, two proposed Diels-Alder reactions are supposed to be involved in the skeleton construction of  1  and  2 .

Two new 5/6/6 polyketide-amino acid hybrids from a genetic mutant of Periconia sp. F-31