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In this study, electrochemically generated free chlorine (EC/Cl2) was activated by UV irradiation with a light emitting diode (LED) lamp at 275 nm to degrade acetaminophen (AAP, 2 μM) in aqueous solution. The potential at a RuO2-IrO2/Ti plate anode was set at 1.5 V vs. the Ag/AgCl electrode. Chlorine was in situ generated in the presence of Cl杴 at the anode and then it was transformed into various active species such as 晑OH and reactive chlorine species (RCS) under UV-LED irradiation. The degradation of AAP was investigated using batch tests, evaluating the influence of different experimental conditions such as NaCl concentration, phosphate buffer saline concentration, irradiation time and solution pH, keeping constant the UV-LED power and temperature. Results show that AAP could be completely degraded by the hybrid process with a high mineralization ratio (73%), and the degradation process followed a pseudo-first-order kinetics. The value of the Electric Energy per Order (EEO) = 1.272 kWh m杴3 order?, which is lower than the energy consumption of some other UV-based processes for AAP degradation. Adding 1 mM HCO3杴 ions slightly decreased the rate of AAP degradation. Luminescent bacteria experiment revealed that the acute toxicity of the reacted solution could be greatly reduced and the ecological risk was effectively abated. The scavenging assay shows that RCS plays a key role in the AAP degradation. The intermediate products were identified, and possible degradation routes were proposed. The system can advantageously replace conventional UV mercury lamp based ones in the degradation of microorganic pollutants.

Acetaminophen degradation in aqueous solution by the UV-LED-EC/Cl 2 process