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Streptomyces griseocarneus  R132 is an actinobacterium capable of controlling fungi in sweet peppers. The crude  S. griseocarneus  R132 methanol extract was fractionated in a polystyrene-divinylbenzene column eluted with 20–100% acetone gradient. Compound  1  isolated from the 60% fraction was identified as 4-chlorocinnamic acid. This fraction and 4-chlorocinnamic acid inhibited  Colletotrichum gloeosporioides  growth by 28% and 65%, respectively, and reduced the diameter of lesions caused by the phytopathogen in  Capsicum annuum  L. fruits by 33.19% and 31.92%, respectively. The isolated 4-chlorocinnamic acid was not toxic to MRC-5 fibroblasts.

Isolation of 4-chlorocinnamic acid from Streptomyces griseocarneus R132, and its inhibition activity against sweet pepper postharvest anthracnose