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The fibre–matrix interface represents a vital element in the development and characterisation of fibre-reinforced polymers (FRPs). Extensive ranges of interfacial properties exist for different composite systems, measured with various interface characterisation techniques. However, the discrepancies in interfacial properties of similar fibre–matrix systems have not been fully addressed or explained. In this review, first, the interface-forming mechanisms of FRPs are established. Following a discourse on three primary factors that affect the fibre–matrix interface, the four main interface characterisation methods (single-fibre fragmentation, single-fibre pull-out, microbond and fibre push-in/-out tests) are described and critically reviewed. These sections review various detailed data reduction schemes, numerical approaches, accompanying challenges and sources of reported scatter. Finally, following the assessment of several infrequent test methods, comprehensive conclusions, prospective directions and intriguing extensions to the field are provided.

Methods and models for fibre–matrix interface characterisation in fibre-reinforced polymers: a review