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The combination of two neutral CHON reagents, a lipophilic phenanthroline dicarboxamide and a hydrophilic diglycolamide, resulted in a synergistic separation of adjacent light lanthanides in nitrate medium as the ligands present a reversed lanthanide selectivity. Separation factors higher than 7 were obtained for the pair Pr/Nd, which is one of the highest values reported in the literature.

Combining a Lipophilic Phenanthroline Carboxamide and a Hydrophilic Diglycolamide to Increase the Separation Factors of Adjacent Light Lanthanides