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A selective extraction process for recovering vanadium (IV) over chromium was proposed with use of a mixed extractant consisting of di(2-ethylhexyl) phosphate (D2EHPA) and tri- n -butyl phosphate (TBP). The influence of various factors, which included the initial aqueous pH value, the concentration of leach solution and D2EHPA, phase ratio (O/A), extraction equilibrium time and extraction temperature in the extraction process on the separation of V and Cr was investigated. Under the condition of the optimum extraction, vanadium extraction was above 94.0%. Meanwhile, under the optimum stripping conditions, the vanadium stripping was above 93.0% utilizing 1.5 mol/L sulfuric acid as the effective stripping reagent. The regeneration and reusability of the loaded organic phases after stripping were discussed. In addition, continuous three-stage extraction and stripping strategy indicated that the aggregate loss of vanadium was 0.885% and that the purity of vanadium was more than 99.9%. Under the condition of the optimum precipitation, when the pH value of the stripping solution was adjusted to 7.0 with ammonia water, the precipitation efficiency reached 99.93%. The calcination conditions (above 680 °C in air) were finally determined by TG-DTA and TG-MS experiments, and the V 2 O 5  obtained by calcination was characterized by XRD. Additionally, a method for detecting impurity elements in vanadium matrix without interference was established. The recovery technology has practical significance in enlarging production scale, reducing specific energy consumption and cost, and realizing automatic control in vanadium leaching process.

Selective Solvent Extraction of Vanadium Over Chromium from Alkaline Leaching Solution of Vanadium Slag by D2EHPA/TBP