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The EuF 3 -doped BaZrF 6 -NaPO 3  system with different component ratios was synthesized and studied. Phosphate and fluorozirconate glassy phases were formed in the system simultaneously, while europium ions were localized in both the glass matrices. Glasses and glass-ceramics containing crystals of NaZr 2 (PO 4 ) 3  or BaZr 2 F 16  were obtained. Luminescence activated by Eu 3+  was found in both glasses and glass-ceramics.

Thermal Behavior and Photoluminescence Properties of Glassy Objects in the System of BaZrF 6 -NaPO 3 -EuF 3