English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

1,4-disubstituted 1H-1,2,3-triazoles  L  was successfully synthesised using a catalyst-free click reaction between an internal alkyne and an azide compound. Refluxing click product  L  and palladium chloride in a homogeneous mixed solvent led to the formation of the non-covalent palladium chloride complex  PdCl 2 -L 2, which was characterised by X-ray crystallographic analysis of the template compound, indicating that the complex adopts predominant trans-trans isomeric orientations. The two compounds showed a typical fan-shaped texture of the lamellar mesophase. Because of weak Pd-N coordination bond connections,  PdCl 2 -L 2is a monotropic liquid crystal with a narrower mesomorphic temperature range and relatively poorer thermal stability than ligand  L . Furthermore, both  L  and the complex dimer can self-assemble into strip-shaped nanostructures on the oriented graphite substrate surface.

1,2,3-Triazole lamellar liquid crystal and its non-covalent palladium complex dimer: structure, mesomorphism and self-assembly properties