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The pearlite formed in 100Mn13 high carbon high manganese steel after 1323 K water toughening subsequently 923 K aging treatment is studied by transmission electron microscope and high-resolution technique. The results show that the pearlite is composed of three phases, which are M 3 C lamellae, M 7 C 3  lamellae, and ferrite lamellae, respectively, with the orientation relationships of () α ∥() M7C3 , () α ∥() M3C , () M3C ∥() M7C3 , [] M3C ∥[] M7C3 ∥[] α . And M 7 C 3  is formed at the phase interface between M 3 C and α. The growth physical model of three-phase pearlite is proposed.

Morphology and formation of three-phase pearlite in an aged 100Mn13 steel