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As a product of photosynthesis, the storable chemical energy in the form of carbohydrates inspires the people engaged in renewable energy research to mimic the natural process. This may be the reduction of the proton or carbon dioxide to produced fuels e.g., hydrogen or CH4 and CH3OH or other chemical feed stocks e.g., HCOOH, CO32-. (COOH)2. This replication of the natural process is known as Artificial Photosynthesis. In either case water oxidation is mandatory. Herein, we discuss brief mechanism of photosynthesis, emphasizing the role of Water Oxidation Catalyst (WOC). Literature on Manganese based WOC is presented with their characteristic features.

Manganese based Molecular Water Oxidation Catalyst: From Natural to Artificial Photosynthesis