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Integrated gasification combined cycle (IGCC) power generation is touted as a cost-effective technology for combining electricity generation with carbon capture. For IGCC carbon capture, membrane technology is ideally suited owing to its low energy requirements and operational simplicity. This paper describes the development of polymeric membranes for CO 2  removal in IGCC plants and reviews both H 2 -selective and CO 2 -selective membranes. First, the fundamentals of CO 2 /H 2  separation using polymeric membranes are presented along with their implications for the performances of H 2 -selective and CO 2 -selective polymers. Popular H 2 -selective and CO 2 -selective polymers that have been proposed for IGCC carbon capture are evaluated and compared. Benefits and drawbacks of each membrane type are discussed. Strategies that have resulted in improved performance are highlighted.

Recent advances in polymeric membranes for carbon dioxide capture from syngas