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Densities  (ρ)  and speeds of sound  (u)  and viscosities ( η ) of binary mixtures of 2-methoxy aniline with aniline, N-methyl aniline and N, N-dimethyl aniline including those of pure liquids, over the entire composition range were measured at temperatures (303.15, 308.15 and 313.15) K and 101.3 kPa. Using the experimental data, the excess volume ( V E) and excess isentropic compressibility ( κ sE), deviation in viscosity (Δ η ), excess partial molar volumes,andand excess partial molar isentropic compressibilities,andof the components at infinite dilution were calculated. These values indicate the formation of intermolecular hydrogen bonding (N-HO = C) between the hydrogen atom of amine group of aniline  / N-methyl aniline /N, N-dimethyl aniline and the oxygen atom of carbonyl group of 2-methylcyclohexanone in the binary liquid mixtures.

international journal of ambient energy

Investigation of ketonic effect in molecular interactions of 2-methylcyclohexanone with aniline, N-methyl aniline and N,N-dimethyl aniline at various temperatures