English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

A metal-organic framework MIL-101(HPW) was synthesized by hydrothermal reaction, and phosphomolybdic acid (HPMo) was synthesized by its precursor solution. Then (Pd + Pt)/HPMo/MIL-101(HPW) with different wt% were prepared by the impregnation method. The synthesized samples were characterized by XRD, FT-IR, NH 3 -TPD, N 2  adsorption, FESEM, and TGA, and their performances were investigated in n-hexane isomerization. Under the optimized operating conditions (temperature of 180 °C, H 2 /nC 6  molar ratio of 2, and WHSV of 3 h −1 ), the appropriate yield for the nC 6  isomerization was provided. The (0.2%Pd + 0.3%Pt)/50%HPMo/MIL-101(HPW) sample showed a lifetime of 720 min with 92.5% iC 6  selectivity and 75.3% nC 6  conversion. Kinetic modeling of the n-hexane isomerization reaction was also performed, in which the classical bifunctional mechanism was used to calculate the kinetic parameters. The validity of the bifunctional behavior was proved by the high value of the statistical correlation coefficient of this model. The apparent activation energy of this mechanism was calculated at 42.5 kJ mol −1 .

chemical engineering communications

Catalytic performance and kinetic modeling of n-hexane isomerization over phosphomolybdic acid (HPMo) combining palladium and platinum supported on metal-organic framework MIL-101(HPW)