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Two solvent-induced bis(phenoxo)-acetate-bridged binuclear Ni(II) complexes, [Ni 2 (L)( µ -OAc)(CH 3 OH)] ( 1 ) and [Ni 2 (L)( µ -OAc)(H 2 O)] ( 2 ), were synthesized with a bis(salamo)-like ligand H 3 L and Ni(OAc) 2 ·4H 2 O in two different alcohol solvents (methanol and ethanol). Complexes  1  and  2  were described by elemental analyses, single crystal X-ray diffraction, IR spectra, UV–vis spectra and fluorescence spectra. Complexes  1  and  2  have analogous crystal structures, but the non-covalent interactions are distinct. The one-dimensional chain of  1  is formed by π–π interactions, and the three-dimensional supramolecular network structure of  2  is formed by intermolecular hydrogen bonding interactions. In addition, fluorescence experiments indicated that the fluorescence of  1  and  2  undergoe a significant quenching compared to H 3 L. Intermolecular forces were investigated using Hirshfeld surface analysis. DFT calculations showed that  1  and  2  have high chemical reactivity and low kinetic stability.

The investigation of two bis(phenoxo)-acetate-bridged binuclear nickel(II) complexes driven by different alcohol solvents