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A new thiophenic alkynylplatinum(II) terpyridyl complex [ t BuArC≡CPt(tpy)]PF 6  (tpy = 2,2′:6′,2″-terpyridine; Ar = [(MeC 4 H 2 S)(C≡C)] 2 C 6 H 2 ) has been synthesized in five steps in 45% total yield. The photophysical properties were studied by steady-state spectroscopy and transient spectroscopy and obvious metal-metal interactions and π-π stacking were found in a series of solvents. Concentration dependent emission data show that the complex exhibited aggregation-induced fluorescence enhancement at low concentrations while aggregation-induced fluorescence quenching at high concentrations. The complex displayed biexponential decays with lifetimes in the range of nanoseconds in dilute dichloromethane and acetonitrile solutions.

A thiophenic alkynylplatinum(II) terpyridyl complex: synthesis and photophysical properties