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Cadmium(II) complexes of  N , N ′-diarylformamidine dithiocarbamate of the general formula [Cd-( L ) 2 ] ( L  =  N , N '-bis(2,6-dimethylphenyl)formamidine dithiocarbamate  L1  ( 1 ),  N , N '-bis(2,6-disopropylphenyl)formamidine dithiocarbamate  L2  ( 2 ),  N '-(2,6-dichlorophenyl- N -(2,6-dimethylphenyl)formamidine dithiocarbamate  L3  ( 3 ),  N '-(2,6-dichlorophenyl)- N -(2,6-diisopropylphenyl)formamidine dithiocarbamate  L4  ( 4 ) and their 2,2-bipyridine (bipy) adducts, [Cd-( L1 ) 2 bipy] ( 5 ), [Cd-( L2 ) 2 bipy] ( 6 ), [Cd-( L3 ) 2 bipy] ( 7 ), [Cd-( L4 ) 2 bipy] ( 8 )) have been synthesized and characterized using various spectroscopic and analytical techniques. For one of the 2,2-bipyridine adducts, the molecular structure was determined using single crystal X-ray structure as a six-coordinate Cd(II) complex in which two pairs of sulfur atoms from two dithiocarbamate ligands and a pair of nitrogen atoms from bipy completed the distorted octahedral geometry. Complexes  1 ,  3  and  5  were used as single source precursors for formation of octadecylamine capped cadmium nanoparticles,  CdS1 ,  CdS3  and  CdS5 . HR-TEM images of as-synthesized  CdS1 ,  CdS3  and  CdS5  particles are nano-spherical in shape with size distributions ranging between 4 and 9 nm. The as-synthesized CdS nanoparticles were used as photocatalysts for degradation of crystal violet, with degradation efficiency of 75-84% and rate constants of 0.0050, 0.0043 and 0.0039 min −1  for  CdS1 ,  CdS3  and  CdS5 , respectively.

journal of coordination chemistry

Photodegradation of crystal violet dye in water using octadecylamine-capped CdS nanoparticles synthesized from Cd(II)  N,N ′-diarylformamidine dithiocarbamates and their 2,2-bipyridine adducts