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Nine new cyanide complexes, {[Cu(aepy) 2 M(µ-CN)(CN) 3 ]⋅2H 2 O} n  [M(II) = Ni ( 1 ), Pd ( 2 ) or Pt ( 3 )], [Zn(aepy) 2 M(µ-CN)(CN) 3 ] n  [M = Ni ( 4 ), Pd ( 5 ) or Pt ( 6 )] and [Cd(aepy) 2 M(µ-CN)(CN) 3 ] n  [M(II) = Ni ( 7 ) or Pd ( 8 )] and (Haepy) 2 [Pt(CN) 4 ] ( 9 ) (aepy = 2-(2-aminoethyl)pyridine), were synthesized and characterized structurally using single crystal X-ray diffraction, vibrational spectroscopy, thermal and elemental analyses. The structure analyses revealed that cyanide complexes  1 – 3  for Cu(II) and  4 – 6  for Zn(II) are heterobinuclear clusters, whereas the two Cd(II) complexes  7  and  8  are infinite one-dimensional coordination polymers. In heterometallic complexes  7  and  8 , the Cd(II) ions are located on a center of symmetry and are coordinated by two nitrogens from cyanide ligands and four nitrogens from aepy ligands, thus showing a distorted octahedral geometry. In  1 – 9 , the intermolecular N–H⋅⋅⋅N hydrogen bonds or/and C–H⋅⋅⋅M interactions (M = Ni(II), Pd(II) and Pt(II)) generate 3D supramolecular networks.

Nine new tetracyanometallate(II) complexes with 2-(2-aminoethyl)pyridine: synthesis, crystal structures and spectroscopic studies