English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

Two copper(I) complexes, [Cu(bdppmapy)(BTZ)]BF 4  ( 1 ) and [Cu(bdppmapy)(BTZ)]ClO 4  ( 2 ) (bdppmapy = N,N-bis[(diphenylphosphino)methyl]-2-pyridinamine, BTZ = 2,2-bithiazole), have been synthesized in mixed CH 3 OH and CH 2 Cl 2  (1:1, V/V) and characterized by single-crystal X-ray diffraction, elemental analysis, IR,  1 H NMR and  31 P NMR spectroscopy, fluorescence spectra and terahertz time-domain spectroscopy (THz-TDS). Complex  1 , a mononuclear complex, was generated by the reaction of [Cu(CH 3 CN) 4 ]BF 4  and bdppmapy with BTZ in a 1:1:1 molar ratio. In  1 , the center Cu(I) forms a distorted tetrahedral geometry by coordinating with the diphosphine ligand (bdppmapy) and N-ligands BTZ. Complex  2  was obtained by reacting [Cu(CH 3 CN) 4 ]ClO 4  and bdppmapy with BTZ in a 1:1:1 molar ratio. In  2 , the bdppmapy and BTZ ligands chelate Cu(I). Luminescent spectra show that the emission mechanism is ascribed to metal-to-ligand charge transfer (MLCT). Terahertz time-domain spectroscopy was also used to characterize these two complexes.

Synthesis, spectral properties and terahertz time domain spectroscopy of two copper(I) complexes based on bisphosphine and bisazo ligands