English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Triple oxidative addition reactions of [M 0 (styrene)(PMe 3 ) 2 ] (M = Pd/Pt) with C 3 -symmetric star-shaped molecules containing 1-, 3-, and 5-thiophene-substituted benzene, in 1:0.3 ratio, afforded new Pd(II) and Pt(II) trinuclear complexes in suitable yields. Analogous trinuclear complexes were formed by similar reactions of thiophenyl halide derivatives containing triazine or triphenylamine cores. Alternatively, a trinuclear Pd(II) complex was obtained by oxidative addition of a Pd(0) complex (synthesized from allyl(cyclopentadienyl) palladium(II), [(η 5 -C 5 H 5 )Pd(η 3 -C 3 H 5 )] with PEt 3 . Sonogashira-type coupling between trinuclear Pt(II) halides (containing C 3 -symmetric conjugated thiophenes) and alkynes, in the presence of cuprous halide and diethylamine, afforded alkynyl-containing trinuclear Pt(II) complexes with extended π-conjugation. Insertion reactions of organic isocyanides (CN-R) with trinuclear Pd(II) complexes yielded trinuclear Pd(II) imidoyl complexes by insertion of CN-R into Pd-carbon (thiophene) bonds. Reactions of trinuclear Pt(II) halides with Ag(OCOCF 3 ) and NaN 3  formed pseudohalogen-containing Pt(II) complexes.

journal of coordination chemistry

Star-shaped Pd(II) and Pt(II) complexes containing C 3 -symmetric conjugated thiophenes: Synthesis, characterization, and chemical reactions with organic unsaturated molecules