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A two-dimensional (2D) chiral heterometallic Zn(II)-Cd(II) metal-organic framework (MOF), {[(CdI 2 ( ZnL ) 2 ·DMF} n  ( 1 ,  H 2 L  =  (R,R)-N,N '-bis(3-(4-pyridyl)salicylidene)-1,2-cyclohexanediamine, DMF =  N , N -dimethylformamide), was synthesized with predesigned chiral metallosalen  ZnL  and CdI 2  via solvothermal reaction. MOF  1  crystallizes in the orthorhombic chiral space group  P 2 1 2 1 2 and exhibits a 2D chiral framework consisting of right ( P ) handed 2 1  helices. Topological analysis indicates that the 2D structure of  1  could be simplified as a uninodalsqltopology. The luminescence experiment revealed that MOF  1  showed intense circularly polarized luminescence (CPL), suggesting that it can be a potential CPL material.

A chiral Salen-based Zn(II)-Cd(II) heterometallic metal-organic framework: synthesis, crystal structure, and optical properties